彭媛, 李娜, 王杏, 王婧, 杜苏蕾, 杨雪, 张稼, 刘敏. 盐酸改性树枝生物炭对四环素的吸附研究J. 内江师范学院学报, 2026, 41(10): 39-46. DOI: 10.13603/j.cnki.51-1621/z.2026.10.006
    引用本文: 彭媛, 李娜, 王杏, 王婧, 杜苏蕾, 杨雪, 张稼, 刘敏. 盐酸改性树枝生物炭对四环素的吸附研究J. 内江师范学院学报, 2026, 41(10): 39-46. DOI: 10.13603/j.cnki.51-1621/z.2026.10.006
    PENG Yuan, LI Na, WANG Xing, WANG Jing, DU Sulei, YANG Xue, ZHANG Jia, LIU Min. Adsorption of tetracycline antibiotics in water by hydrochloric acid modified biocharJ. Journal of Neijiang Normal University, 2026, 41(10): 39-46. DOI: 10.13603/j.cnki.51-1621/z.2026.10.006
    Citation: PENG Yuan, LI Na, WANG Xing, WANG Jing, DU Sulei, YANG Xue, ZHANG Jia, LIU Min. Adsorption of tetracycline antibiotics in water by hydrochloric acid modified biocharJ. Journal of Neijiang Normal University, 2026, 41(10): 39-46. DOI: 10.13603/j.cnki.51-1621/z.2026.10.006

    盐酸改性树枝生物炭对四环素的吸附研究

    Adsorption of tetracycline antibiotics in water by hydrochloric acid modified biochar

    • 摘要: 为实现园林废弃物资源化利用与水体四环素类抗生素高效去除,本研究以园林废弃杨树树枝为原料,经高温热解制备原始生物炭(BC),并通过盐酸改性得到改性生物炭(HBC).采用SEM、XRD、FTIR等表征技术分析材料理化性质,以盐酸四环素为目标污染物,系统探究投加量、pH、温度等因素对吸附效果的影响,并结合吸附等温线与动力学模型揭示吸附机理.结果表明,盐酸改性可有效去除BC中 CaCO3等无机灰分,显著优化孔隙结构(孔径分布更均匀)并丰富表面含氧官能团(C-O、-OH、C=O等).HBC对盐酸四环素的吸附性能显著优于BC,吸附率从50.29% 提升至82%,最佳吸附条件为投加量2.4 g/L、pH=3、温度35 ℃,此时最大吸附量达76.61 mg/g.吸附过程符合Langmuir 等温模型(R2=0.984~0.991)和拟二级动力学模型(R2=0.960),表明吸附以单分子层化学吸附为主,核心机制包括静电吸引、氢键及π-π相互作用.本研究为园林废弃物高值化利用及水体抗生素污染控制提供了经济可行的技术方案,兼具环境与经济效益.

       

      Abstract: In this study, waste poplar branches from landscaping were used as raw material to prepare pristine biochar (BC) via high-temperature pyrolysis, and hydrochloric acid-modified biochar (HBC) was obtained through chemical modification. The adsorption performance and mechanism of these biochars for tetracycline hydrochloride (TCH) in aqueous solutions were systematically investigated. Results indicated that hydrochloric acid modification effectively removed inorganic ash fractions (e.g., CaCO3) from the biochar, significantly increased the pore size, and enriched surface oxygen-containing functional groups (such as C-O, -OH, and C=O), thereby enhancing its adsorption capacity. Under the optimal adsorption conditions (dosage = 2. 4 g/L, pH=3, temperature=35℃), the adsorption rate of TCH by HBC increased from 50.29% (for BC) to 82%, with a maximum adsorption capacity of 76.61 mg/g. The adsorption behavior followed the Langmuir isotherm model and pseudo-second-order kinetic model, suggesting that the process is monolayer chemisorption. The primary adsorption mechanisms include electrostatic attraction, hydrogen bonding, and π-π interactions. This study provides a feasible approach for the resource utilization of landscaping waste and the efficient removal of tetracycline antibiotics from water bodies, achieving both environmental and economic benefits.

       

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