林成. 功率增强型的全光式QEPAS痕量气体检测系统研究[J]. 内江师范学院学报, 2024, 39(6): 60-65. DOI: 10.13603/j.cnki.51-1621/z.2024.06.010
    引用本文: 林成. 功率增强型的全光式QEPAS痕量气体检测系统研究[J]. 内江师范学院学报, 2024, 39(6): 60-65. DOI: 10.13603/j.cnki.51-1621/z.2024.06.010
    LIN Cheng. All-optical QEPAS trace gas senor employing an optical amplification technique[J]. Journal of Neijiang Normal University, 2024, 39(6): 60-65. DOI: 10.13603/j.cnki.51-1621/z.2024.06.010
    Citation: LIN Cheng. All-optical QEPAS trace gas senor employing an optical amplification technique[J]. Journal of Neijiang Normal University, 2024, 39(6): 60-65. DOI: 10.13603/j.cnki.51-1621/z.2024.06.010

    功率增强型的全光式QEPAS痕量气体检测系统研究

    All-optical QEPAS trace gas senor employing an optical amplification technique

    • 摘要: 石英增强光声光谱技术由于具有灵敏度高、噪声免疫能力强、体积小等优点,成了一种备受关注的痕量气体检测技术.本文设计了一种全光式QEPAS痕量气体检测系统,采用共振频率为32.7 kHz的石英音叉作为声传感器,结合光功率放大技术,实现了系统信号幅值的极大提高;以具有工作点自稳定特性的光纤珐珀干涉仪作为振动解调单元,极大地提高了系统的稳定性.以C2H2作为检测对象,采用波长调制和二次谐波解调技术,优化得到系统的最佳调制深度为0.171 cm-1、最佳激光位置距离音叉底部2.9 mm,最终得到QEPAS信号随C2H2浓度线性变化,其线性度为0.998,系统检测极限为30.3 ppb,由此得到系统的归一化等效噪声系数为2.51×10-8 cm-1·W·Hz-1/2.最后在相同条件下,通过1小时连续工作测试验证了系统具有极好的稳定性.

       

      Abstract: Quartz-Enhanced Photoacoustic Spectroscopy (QEPA) technology has become a kind of trace gas detection technology due to its advantages of high sensitivity, strong immunity to noise and compact size. An all-optical QEPA trace gas detection system was designed. A quartz tuning fork with a resonant frequency of 32.7 kHz was employed as the acoustic sensor, and the system signal amplitude was greatly enhanced by employing an optical power amplification technology. A fiber-optic Fabry-Perot interferometer with self-stabilizing characteristics was used as the vibration demodulation unit, significantly improving system stability. Acetylene (C2H2) was selected as the target gas for detection. A tunable semiconductor laser with a output wavelength of 1.5 μm was used as the excitation light source. By combining wavelength modulation and second harmonic demodulation techniques, the optimal modulation depth was determined to be 0.171 cm-1, and the optimal distance between the laser position and the bottom of the tuning fork was found to be 0.8 mm. The QEPAS signal exhibited linear variation with C2H2 concentration, with a linearity of 0.998. The system detection limit was 30.3 ppb, corresponding to a normalized equivalent noise coefficient of 2.51×10-8 cm-1·W·Hz-1/2. Finally, under the same conditions, a continuous working test for one hour was conducted, verifying the excellent stability of the system.

       

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